聚苯胺長效防腐水性環(huán)保涂料的研制及性能研究
2013-06-03 14:07:38
作者:康先進等來源:=$docheckrep[1]?ReplaceBefrom($ecms_gr[befrom]):$ecms_gr[befrom]?>
摘要:采用原位化學(xué)合成法制備對甲苯磺酸摻雜的聚苯胺/二氧化硅復(fù)合材料,并用紅外光譜、掃描電鏡和透射電鏡表征其結(jié)構(gòu),以合成的聚苯胺/二氧化硅為功能組分,丙烯酸水性乳液為成膜物質(zhì),制成水性環(huán)保防腐涂料。用電化學(xué)測試技術(shù)研究復(fù)合水性防腐涂料對碳鋼基材的防護效果。結(jié)果表明,復(fù)合水性防腐涂料使金屬基體的腐蝕電位正移,具有較好的鈍化效果,增強了耐蝕性。
Absract:Polyaniline-SiO2 was in situ synthesized and doped by p-toluenesulfonic acid (p-TSA). The composites were characterized by FTIR, SEM and TEM. The corrosion performance of polyaniline-SiO2 pigmented waterborne coating on carbon steel was studied by electrochemical testing technique in 3.5% NaCl solution. The tested results showed that a passivation effect and a positive shift of corrosion potential occurred due to the application of coating on metals and the anticorrosion property was enhanced.
Key Word:polyaniline ,SiO2,waterborne coating,polarization
Absract:Polyaniline-SiO2 was in situ synthesized and doped by p-toluenesulfonic acid (p-TSA). The composites were characterized by FTIR, SEM and TEM. The corrosion performance of polyaniline-SiO2 pigmented waterborne coating on carbon steel was studied by electrochemical testing technique in 3.5% NaCl solution. The tested results showed that a passivation effect and a positive shift of corrosion potential occurred due to the application of coating on metals and the anticorrosion property was enhanced.
Key Word:polyaniline ,SiO2,waterborne coating,polarization
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